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Thiyl radicals are readily formed through homolytic cleavage of the sulfhydryl S-H bond due to low bond dissociation energies of around 87 kcal mol −1 (Dénès et al., 1 or the water-soluble 2,2'-azobis[2-(2-imidazolin-2-yl)propane]-dihydrochloride (VA044) 2 radical initiator (Figure 1)

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In psoriasis, adjuvant therapy with Vitamin D analogues has been shown to reduce disease severity scores and modulate the Th17/IL-23 inflammatory axis, suggesting potential utility in chronic immune-dysregulated dermatoses [258, 259]